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Iwase, Hiroki*; Sawada, Shinichi; Yamaki, Tetsuya; Maekawa, Yasunari; Koizumi, Satoshi
International Journal of Polymer Science, 2011(2011), p.301807_1 - 301807_7, 2011/00
Times Cited Count:12 Percentile:38.06(Polymer Science)Preirradiation graft polymerization of styrene in a poly(tetrafluoroethylene) (PTFE) film was examined by time-resolved small-angle neutron scattering (SANS). A crosslinked PTFE film, thickness of which is about 50m, was irradiated by -ray and immersed in a mixed solvent of styrene monomer and toluene. SANS elucidated that graft polymerization proceeds by two reaction processes (I) and (II). In process (I) at 0200 min, graft polymerization occurs at an interface between crystalline and amorphous PTFE domains and the grafted polystyrene segregates from PTFE, forming a thin layer with a sharp interface. In process (II) at 200600 min, grafted PS layer starts to bridge between crystalline domains. At the end of process (II), 40% of total crystalline PTFE domain is covered by the grafted PS chains.
Wach, R.; Sugimoto, Masaki; Lam, N. D.; Yoshikawa, Masahito
Proceedings of 8th SPSJ International Polymer Conference (IPC 2005) (CD-ROM), 60 Pages, 2005/07
no abstracts in English
Oshima, Akihiro; Seguchi, Tadao; Tabata, Yoneho
Polymer International, 48, p.996 - 1003, 1999/00
Times Cited Count:24 Percentile:68.24(Polymer Science)no abstracts in English
Oshima, Akihiro; Seguchi, Tadao; Tabata, Yoneho*
Proceedings of IUPAC World Polymer Congress 37th International Symposium on Macromolecules (MACRO 98), P. 56, 1998/00
no abstracts in English
Oshima, Akihiro; Ikeda, Shigetoshi*; Seguchi, Tadao; Tabata, Yoneho*
Preprints of 6th SPSJ International Polymer Conference, P. 237, 1997/00
no abstracts in English